Câu 3 : 

\(n_{HCl}=\dfrac{10\cdot21.9\%}{36.5}=0.06\left(mol\right)\)

\(AO+2HCl\rightarrow ACl_2+H_2O\)

\(0.03........0.06\)

\(M=\dfrac{2.4}{0.03}=80\left(\dfrac{g}{mol}\right)\)

\(\Rightarrow A=64\)

\(CuO\)

Câu 2 : 

$n_{CuO} = \dfrac{1,6}{80} = 0,02(mol)$
$n_{H_2SO_4} = \dfrac{100.20\%}{98} = \dfrac{10}{49}$

$CuO + H_2SO_4 \to CuSO_4 + H_2O$

$n_{CuO} < n_{H_2SO_4}$ nên $H_2SO_4 dư

Theo PTHH :
$n_{CuSO_4} = n_{H_2SO_4\ pư} = n_{CuO} = 0,02(mol)$
$m_{dd} = 1,6 + 100 = 101,6(gam)$

Vậy :

$C\%_{CuSO_4} = \dfrac{0,02.160}{101,6}.100\% = 3,15\%$

$C\%_{H_2SO_4\ dư} = \dfrac{100.20\% - 0,02.98}{101,6}.100\% = 17,6\%$

CÂU 2

m_H2SO4=100.20%=20(g)

n_H2SO4=20/98=0,2(mol)

n_CuO=1,6/80=0,02(mol)

PTHH : CuO+H₂SO₄-->CuSO₄+H₂O(1)

bài        0,02    0,2         0,02       0,02             (mol)

có:0,02/1<0,2/1---->CuO hết,H₂SO₄ dư

từ pt(1)-->n_CuSO4=0,02(mol)--->m_CuSO4=0,02.160=3,2(g)

khối lượng dd sau pư là:1,6+100-0,02.18=101,24(g)

-->C_%(CuSO4)=3,2/101,24.100%=3,16%

CÂU 3

m_HCl=10.21,9%=2,19(g)

-->n_HCl=2,19/36,5=0,06(mol)

gọi tên KL là M.M_M=M(g/mol)

PTHH: MO+2HCl-->MCl₂+H₂O(1)

          0,03     0,06                       (mol)

từ pt 1-->n_MO=0,03(mol)

--->M_MO=2,4/0,03=80(g/mol)

--->M=80-16=64(g/mol)

--->M là Cu

Ta có: \(n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\)

\(n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3\left(mol\right)\)

PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

Dung dịch A gồm: CuSO₄ và H₂SO₄ dư

\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

Đề có cho dữ kiện gì liên quan đến dd NaOH không bạn nhỉ?

\(n_{H_2SO_4}=\dfrac{200.19,6}{100.98}=0,4mol\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4\left(A\right)}=n_{CuO}=n_{H_2SO_4}=0,4mol\\ n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\\Rightarrow\dfrac{0,4}{1}>\dfrac{0,3}{1}\Rightarrow CuSO_4.pư.không.hết\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

0,3mol        0,6mol                                        0,3mol

\(m_{ddB}=0,4.80+200+0,6.40-29,4=226,6g\\ C_{\%Na_2SO_4\left(B\right)}=\dfrac{0,3.142}{226,6}\cdot100=18,8\%\)

a)

$CuO + H_2SO_4 \to CuSO_4 + H_2O$
$ZnO + H_2SO_4 \to ZnSO_4 +H_2O$

b) Gọi $n_{CuO} = a(mol) ; n_{ZnO} = b(mol) \Rightarrow 80a +81b = 12,1(1)$

Theo PTHH :

$n_{H_2SO_4} = a + b = \dfrac{73,5.20\%}{98} = 0,15(mol)(2)$

Từ (1)(2) suy ra : a = 0,05 ; b = 0,1

$\%m_{CuO} = \dfrac{0,05.80}{12,1}.100\% = 33,06\%$

$\%m_{ZnO} = 100\% - 33,06\% = 66,94\%$

\(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\\ n_{H_2SO_4}=\dfrac{19,6\%.200}{98}=0,4\left(mol\right)\\a, ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\\ b,Vì:\dfrac{0,1}{1}< \dfrac{0,4}{1}\\ \Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(p.ứ\right)}=n_{ZnSO_4}=n_{ZnO}=0,1\left(mol\right)\\ n_{H_2SO_4\left(dư\right)}=0,4-0,1=0,3\left(mol\right)\\ \Rightarrow m_{H_2SO_4\left(dư\right)}=98.0,3=29,4\left(g\right)\\ c,n_{ZnSO_4}=0,1.161=16,1\left(g\right)\\ m_{ddsau}=m_{ZnO}+m_{ddH_2SO_4}=8,1+200=208,1\left(g\right)\\ \Rightarrow C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{29,4}{208,1}.100\approx14,128\%\\ C\%_{ddZnSO_4}=\dfrac{16,1}{208,1}.100\approx7,737\%\)

ZnO+H₂SO₄->ZnSO₄+H₂O

0,1-----0,1-------0,1-------0,1 mol

n _ZnO=\(\dfrac{8,1}{81}\)=0,1 mol

m _H2SO4 =39,2g =>n _H2SO4=\(\dfrac{39,2}{98}\)=0,4 mol

=>H2SO4 , dư 0,3 mol

=>m _H2SO4=0,3.98=29,4g

=>C%_H2SO4 dư=\(\dfrac{29,4}{200+0,1.18}\).100=14,568%

=>C% _ZnSO4=\(\dfrac{0,1.161}{200+0,1.18}.100=7,9781\%\)

\(n_{Al}=\dfrac{10,8}{27}=0,4(mol)\\ a,2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow n_{H_2}=n_{H_2SO_4}=0,6(mol);n_{Al_2(SO_4)_3}=0,2(mol)\\ b,V_{H_2}=0,6.22,4=13,44(l)\\ c,m_{dd_{H_2SO_4}}=\dfrac{0,6.98}{9,8\%}=600(g)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,2.342}{10,8+600-0,6.2}.100\%=11,22\%\)

a) \(n_{Al}=\dfrac{m}{M}=\dfrac{10,8}{27}=0,4\left(\text{mol}\right)\)

Phương trình hóa học phản ứng

2Al + 3H₂SO₄ ---> Al₂(SO₄)₃ + 3H₂

_{2          :   3                   : 1               : 3} 

0,4        0,6            0,2             0,6

mol       mol           mol             mol

Thể tích khí H₂ sinh ra là 

\(V=n.22,4=0,6.22,4=13,44\left(l\right)\)

\(m_{Al_2\left(SO_4\right)_3}=n.M=0,2.342=68,4\left(g\right)\)

\(m_{H_2SO4}=n.M=0,6.98=58,8\left(g\right)\)

\(m_{H_2}=n.M=0,6.2=1,2\left(g\right)\)

=> \(m_{ddH_2SO_4}=\dfrac{m_{H_2SO_4}.100\%}{C\%}=\dfrac{58,8.100\%}{9,8\%}=600\)(g)

=> \(m_{\text{dd sau pư}}=m_{ddH_2SO_4}+m_{Al}-m_{H_2}\)

= 600 + 10,8 - 1,2 (g) = 609,6 (g) 

=> \(C\%_{Al_2\left(SO_4\right)_3}=\dfrac{m_{Al_2\left(SO_4\right)_3}}{m_{\text{dd sau pư}}}.100\%=\dfrac{68,4}{609,6}.100\%\)=11,22%

Bài 4 : 

\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)

a) Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)

            1          2              1          1

          0,2        0,4           0,2        0,2

b) \(n_{H2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

\(V_{H2\left(dktc\right)}=0,2.22,4=4,48\left(l\right)\)

c) \(n_{HCl}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)

⇒ \(m_{HCl}=0,4.36,5=14,6\left(g\right)\)

\(C_{ddHCl}=\dfrac{14,6.100}{100}=14,6\)⁰/₀

d) \(n_{ZnCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

⇒ \(m_{ZnCl2}=0,2.136=27,2\left(g\right)\)

\(m_{ddspu}=13+100-\left(0,2.2\right)=112,6\left(g\right)\)

\(C_{ZnCl2}=\dfrac{27,2.100}{112,6}=24,16\)⁰/₀

 Chúc bạn học tốt

Bài 3 : 

\(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)

a) Pt : \(Mg+H_2SO_4\rightarrow MgSO_4+H_2|\)

            1            1                1           1

          0,5          0,5            0,5          0,5

b) \(n_{H2}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)

\(V_{H2\left(dktc\right)}=0,5.22,4=11,2\left(l\right)\)

c) \(n_{H2SO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)

⇒ \(m_{H2SO4}=0,5.98=49\left(g\right)\)

\(C_{ddH2SO4}=\dfrac{49.100}{200}=24,5\)⁰/₀

d) \(n_{MgSO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)

⇒ \(m_{MgSO4}=0,5.120=60\left(g\right)\)

\(m_{ddspu}=12+200-\left(0,5.2\right)=211\left(g\right)\)

\(C_{MgSO4}=\dfrac{60.100}{211}=28,44\)⁰/₀

 Chúc bạn học tốt

Mg+H2SO4->MgSO4+H2

0,5----0,5--------0,5--------0,5

n Mg=12\24=0,5 mol

=>VH2=0,5.22,4=11,2l

=>m H2SO4=0,5.98=49 g

=>C% =49\200.100=24,5g

=>m dd=12+200-0,5.2=211g

=>C%=0,4.120\211.100=22,74885%

\(n_{FeO}=a\left(mol\right),n_{CuO}=b\left(mol\right)\)

\(m_{hh}=72a+80b=19.2\left(g\right)\left(1\right)\)

\(FeO+H_2SO_4\rightarrow FeSO_4+H_2O\)

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(n_{H_2SO_4}=a+b=0.25\left(mol\right)\left(2\right)\)

\(\left(1\right),\left(2\right):a=0.1,b=0.15\)

\(m_{FeO}=0.1\cdot72=7.2\left(g\right)\)

\(m_{CuO}=12\left(g\right)\)

\(C_{M_{FeSO_4}}=\dfrac{0.1}{0.25}=0.4\left(M\right)\)

\(C_{M_{CuSO_4}}=\dfrac{0.15}{0.25}=0.6\left(M\right)\)